𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The chemistry of the N-alkylaldimines. II. The reaction of N-propylpropanaldimine with acid chlorides

✍ Scribed by H. Breederveld

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
324 KB
Volume
79
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

N‐Propylpropanaldimine adds on acid chlorides with formation of the corresponding N(1‐chloropropyl)‐N‐propylamides, which on heating split off hydrochloric acid to yield the N(1‐propenyl)‐N‐propyl derivatives as the final products.

N(1‐Propenyl)‐N‐propylacetamide, N(1‐propenyl)‐N‐propylbenzamide, diethylamino‐(1‐propenylpropylamino)‐dichlorosilane and dichlorophosphor‐N(1‐propenyl)‐N‐propylamidic acid have been prepared by this method.

📜 SIMILAR VOLUMES

The chemistry of the N-alkylaldimines. I
The chemistry of the N-alkylaldimines. I. The reaction of N-alkylaldimines with acetic anhydride
✍ H. Breederveld 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 312 KB

## Abstract N‐Alkylaldimines add on acetic anhydride with the formation of the corresponding N‐alkyl‐N(1‐acetoxyalkyl)‐acetamides, which readily split off acetic acid to yield N‐alkyl‐N(1‐alkenyl)‐acetamides as the final products. N‐Propyl‐N‐vinyl‐, N‐propyl‐N(1‐propenyl)‐ and N‐propyl‐N(1‐butenyl

The reaction of n,n-dibenzylcarbamoyl ch
The reaction of n,n-dibenzylcarbamoyl chloride with n-nitrosohydroxylamine
✍ Masayuki Nakajima; Jean-Pierre Anselme 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 119 KB

SUM!.4ARY: The action 06 N,N-dibenzy1tibamoyL ckeohide (21 on -the bodium da.& 06 N-niattobo-hy&oxy&minti (11 in dhy actiome at he&&ix .&&4 ti pmduc& whobe ,(otmati\_on may be trationaL&d in &amb 06 canbamoylatin aR e&heh oxygen 06 the bididen&zte N-tiobohy&oxy,kmi.mb.

The reaction of tris(trimethylsilyl)sila
The reaction of tris(trimethylsilyl)silane with acid chlorides
✍ M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 268 KB

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb

The Reaction of N,N-Dibenzylcarbamoyl Ch
The Reaction of N,N-Dibenzylcarbamoyl Chloride with Silver Nitrate
✍ Masayuki Nakajima; Jean-Pierre Anselme 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 86 KB 👁 2 views

The reaction of disubstituted carbamoyl chlorides and sulfamoyl chlorides with sodium nitrite in acetonitrile has been shown to afford N-nitrosamines in excellent yields. In 1959, Norris had described the reaction of dialkylcarbamoyl chlorides with silver nitrate: mixtures of dialkylnitramines and