## Abstract N‐Propylpropanaldimine adds on acid chlorides with formation of the corresponding N(1‐chloropropyl)‐N‐propylamides, which on heating split off hydrochloric acid to yield the N(1‐propenyl)‐N‐propyl derivatives as the final products. N(1‐Propenyl)‐N‐propylacetamide, N(1‐propenyl)‐N‐propy
The chemistry of the N-alkylaldimines. I. The reaction of N-alkylaldimines with acetic anhydride
✍ Scribed by H. Breederveld
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 312 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
N‐Alkylaldimines add on acetic anhydride with the formation of the corresponding N‐alkyl‐N(1‐acetoxyalkyl)‐acetamides, which readily split off acetic acid to yield N‐alkyl‐N(1‐alkenyl)‐acetamides as the final products.
N‐Propyl‐N‐vinyl‐, N‐propyl‐N(1‐propenyl)‐ and N‐propyl‐N(1‐butenyl)‐acetamide have been prepared by this method; the infrared spectra are discussed.
📜 SIMILAR VOLUMES
## Abstract The band at about 1400 cm^−1^ in the infrared spectra of N(1‐alkenyl)‐N‐propylamides is assigned to the N‐C‐stretching vibration of the system magnified image
The mechanism of the reaction of 2-picoline N-oxide (I) with acetic anhydride to give 2-acetoxymethylpyridine (II) has been a subject of controversy.'