CIDNP in the reaction of 2-picoline N-oxide with acetic anhydride
✍ Scribed by Hiizu Iwamura; Michiko Iwamura; Toshiaki Nishida; Iwao Miura
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 221 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The mechanism of the reaction of 2-picoline N-oxide (I) with acetic anhydride to give 2-acetoxymethylpyridine (II) has been a subject of controversy.'
📜 SIMILAR VOLUMES
Iron(III) Picolinate-Catalyzed Oxidative Demethylation of N,N-Dimethylaniline with Hydrogen Peroxide in the Presence of Acetic Anhydride. -The Fe(III) picolinate catalyzed oxidation of N,Ndimethylaniline proceeds via two different pathways depending on the presence or absence of Ac 2 O. In the abse
## Abstract N‐Alkylaldimines add on acetic anhydride with the formation of the corresponding N‐alkyl‐N(1‐acetoxyalkyl)‐acetamides, which readily split off acetic acid to yield N‐alkyl‐N(1‐alkenyl)‐acetamides as the final products. N‐Propyl‐N‐vinyl‐, N‐propyl‐N(1‐propenyl)‐ and N‐propyl‐N(1‐butenyl