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ChemInform Abstract: Iron(III) Picolinate-Catalyzed Oxidative Demethylation of N,N-Dimethylaniline with Hydrogen Peroxide in the Presence of Acetic Anhydride.

โœ Scribed by E. KOTANI; T. TAKEYA; H. SHIMIZU; H. EGAWA; T. YAMAMOTO; S. TOBINAGA

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Iron(III) Picolinate-Catalyzed Oxidative Demethylation of N,N-Dimethylaniline with Hydrogen Peroxide in the Presence of Acetic Anhydride.

-The Fe(III) picolinate catalyzed oxidation of N,Ndimethylaniline proceeds via two different pathways depending on the presence or absence of Ac 2 O. In the absence of Ac 2 O, the N-formylation product (II) is predominantly obtained, while in the presence of Ac 2 O the N-acetylative demethylation product (V) is mainly formed. -(KOTANI, E.; TAKEYA,

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ChemInform Abstract: Iron(III)picolinate
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