(Tetrahydrofuran-κO)bis(tri-tert-butoxysilanethiolato-κ2O,S)chromium(II)
✍ Scribed by Ciborska, Anna ;Baranowska, Katarzyna ;Wojnowski, Wiesław
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 247 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Co(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)(NH 3 )], was obtained by the reaction of dimeric [Co{SSi(O t Bu) 3 } 2 (NH 3 )] 2 with 2-ethylpyridine. The Co II atom is coordinated by two S atoms from two silanethiolate ligands and two N atoms, one from ammonia and one from a 2-ethylpyridi
In the title compound, [Zn(C 12 H 27 O 3 SSi) 2 (C 5 H 8 N 2 )]ÁC 3 H 8 O, the Zn II centre is coordinated by the N atom of the 2ethylimidazole ligand and two S and two O atoms of the two thiolate ligands in a trigonal-bipyramidal geometry. The hydroxyl group of the propan-2-ol solvent molecule form
metal-organic papers Acta Cryst. (2006). E62, m3407-m3409 Kropidłowska et al. [Cd(C 12 H 27 O 3 SiS) 2 (C 10 H 8 N 2 )] m3409
In the title compound, [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ], the Cr atom has a trigonal-bipyramidal geometry, with the two tetrahydrofuran molecules in axial positions. metal-organic papers m1104 Ciborska et al. [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ]