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(2-Ethylimidazole-κN)bis(tri-tert-butoxysilanethiolato-κ2O,S)zinc(II) propan-2-ol solvate

✍ Scribed by Dołęga, Anna ;Wieczerzak, Monika ;Baranowska, Katarzyna

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
364 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(C 12 H 27 O 3 SSi) 2 (C 5 H 8 N 2 )]ÁC 3 H 8 O, the Zn II centre is coordinated by the N atom of the 2ethylimidazole ligand and two S and two O atoms of the two thiolate ligands in a trigonal-bipyramidal geometry. The hydroxyl group of the propan-2-ol solvent molecule forms N-HÁ Á ÁO and O-HÁ Á ÁS hydrogen bonds with adjacent molecules, linking them into chains.

Related literature

For an analogous compound with 1-methylimidazole, see Dołe ˛ga et al. (2004).

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