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Ammine(2-ethylpyridine-κN)bis(tri-tert-butoxysilanethiolato-κS)cobalt(II)

✍ Scribed by Pladzyk, Agnieszka ;Baranowska, Katarzyna

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
1021 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Co(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)(NH 3 )], was obtained by the reaction of dimeric [Co{SSi(O t Bu) 3 } 2 (NH 3 )] 2 with 2-ethylpyridine. The Co II atom is coordinated by two S atoms from two silanethiolate ligands and two N atoms, one from ammonia and one from a 2-ethylpyridine molecule. The arrangement of the ligands around the Co II centre facilitates the formation of an intermolecular N-HÁ Á ÁS hydrogen bond.

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(2-Ethylimidazole-κN)bis(tri-tert-butoxy
(2-Ethylimidazole-κN)bis(tri-tert-butoxysilanethiolato-κ2O,S)zinc(II) propan-2-ol solvate
✍ Dołęga, Anna ;Wieczerzak, Monika ;Baranowska, Katarzyna 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 364 KB

In the title compound, [Zn(C 12 H 27 O 3 SSi) 2 (C 5 H 8 N 2 )]ÁC 3 H 8 O, the Zn II centre is coordinated by the N atom of the 2ethylimidazole ligand and two S and two O atoms of the two thiolate ligands in a trigonal-bipyramidal geometry. The hydroxyl group of the propan-2-ol solvent molecule form

μ-trans-1,2-Di-4-pyridylethene-κ2N:N′-bi
μ-trans-1,2-Di-4-pyridylethene-κ2N:N′-bis­[(dimethyl­formamide-κO)bis­(tri-tert-butoxy­silanethiol­ato-κS)cadmium(II)]
✍ Bąkowicz, Julia ;Kropidłowska, Anna ;Turowska-Tyrk, Ilona ;Becker, Barbara 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 293 KB

In the centrosymmetric title complex, [Cd 2 (C 12 H 27 O 3 SSi) 4 -(C 3 H 7 NO) 2 (C 12 H 10 N 2 )], the Cd atom is four-coordinated in a CdNOS 2 core. metal-organic papers Acta Cryst. (2007). E63, m973-m975 Ba ´kowicz et al. [Cd 2 (C 12 H 27 O 3 SSi) 4 (C 3 H 7 NO) 2 (C 12 H 10 N 2 )] m975