The title compound, [Co(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)(NH 3 )], was obtained by the reaction of dimeric [Co{SSi(O t Bu) 3 } 2 (NH 3 )] 2 with 2-ethylpyridine. The Co II atom is coordinated by two S atoms from two silanethiolate ligands and two N atoms, one from ammonia and one from a 2-ethylpyridi
Bis(tri-tert-butoxysilanethiolato-κS)bis(pyrrolidine-κN)cobalt(II)
✍ Scribed by Pladzyk, Agnieszka ;Baranowska, Katarzyna
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 171 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
metal-organic papers Acta Cryst. (2006). E62, m3407-m3409 Kropidłowska et al. [Cd(C 12 H 27 O 3 SiS) 2 (C 10 H 8 N 2 )] m3409
In the centrosymmetric title complex, [Cd 2 (C 12 H 27 O 3 SSi) 4 -(C 3 H 7 NO) 2 (C 12 H 10 N 2 )], the Cd atom is four-coordinated in a CdNOS 2 core. metal-organic papers Acta Cryst. (2007). E63, m973-m975 Ba ´kowicz et al. [Cd 2 (C 12 H 27 O 3 SSi) 4 (C 3 H 7 NO) 2 (C 12 H 10 N 2 )] m975
The title compound, [Cd(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)], is a molecular heteroleptic cadmium thiolate containing an additional 3,5-dimethylpyridine ligand. The Cd II ion is located at the centre of the trigonal bipyramid formed by five atoms, viz. two S, two O and one N. Molecules pack as discrete