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Bis(tri-tert-butoxy­silanethiol­ato-κS)bis­(pyrrolidine-κN)cobalt(II)

✍ Scribed by Pladzyk, Agnieszka ;Baranowska, Katarzyna


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
171 KB
Volume
62
Category
Article
ISSN
1600-5368

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Ammine(2-ethylpyridine-κN)bis(tri-tert-b
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The title compound, [Co(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)(NH 3 )], was obtained by the reaction of dimeric [Co{SSi(O t Bu) 3 } 2 (NH 3 )] 2 with 2-ethylpyridine. The Co II atom is coordinated by two S atoms from two silanethiolate ligands and two N atoms, one from ammonia and one from a 2-ethylpyridi

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metal-organic papers Acta Cryst. (2006). E62, m3407-m3409 Kropidłowska et al. [Cd(C 12 H 27 O 3 SiS) 2 (C 10 H 8 N 2 )] m3409

μ-trans-1,2-Di-4-pyridylethene-κ2N:N′-bi
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In the centrosymmetric title complex, [Cd 2 (C 12 H 27 O 3 SSi) 4 -(C 3 H 7 NO) 2 (C 12 H 10 N 2 )], the Cd atom is four-coordinated in a CdNOS 2 core. metal-organic papers Acta Cryst. (2007). E63, m973-m975 Ba ´kowicz et al. [Cd 2 (C 12 H 27 O 3 SSi) 4 (C 3 H 7 NO) 2 (C 12 H 10 N 2 )] m975

(3,5-Dimethyl­pyridine)bis­(tri-tert-but
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The title compound, [Cd(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)], is a molecular heteroleptic cadmium thiolate containing an additional 3,5-dimethylpyridine ligand. The Cd II ion is located at the centre of the trigonal bipyramid formed by five atoms, viz. two S, two O and one N. Molecules pack as discrete