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Bis(tetra­hydro­furan-κO)tris­(tri-tert-butoxy­siloxy)chromium(III)

✍ Scribed by Ciborska, Anna ;Chojnacki, Jaroslaw ;Wojnowski, Wieslaw

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
147 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ], the Cr atom has a trigonal-bipyramidal geometry, with the two tetrahydrofuran molecules in axial positions. metal-organic papers m1104 Ciborska et al. [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ]

📜 SIMILAR VOLUMES

trans-Bis(acetyl­acetonato-κ2O,O′)mesit­
trans-Bis(acetyl­acetonato-κ2O,O′)mesit­yl(tetra­hydro­furan-κO)vanadium(III)
✍ Imhof, Wolfgang ;Seidel, Wolfgang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 200 KB

In the title compound, [V(C 9 H 11 )(C 5 H 7 O 2 ) 2 (C 4 H 8 O)], the V atom is octahedrally coordinated by two chelating acetylacetonate (acac) ligands in trans positions, one tetrahydrofuran (THF) ligand and one -bonded mesityl group.