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trans-Bis(acetyl­acetonato-κ2O,O′)mesit­yl(tetra­hydro­furan-κO)vanadium(III)

✍ Scribed by Imhof, Wolfgang ;Seidel, Wolfgang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
200 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [V(C 9 H 11 )(C 5 H 7 O 2 ) 2 (C 4 H 8 O)], the V atom is octahedrally coordinated by two chelating acetylacetonate (acac) ligands in trans positions, one tetrahydrofuran (THF) ligand and one -bonded mesityl group.

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Bis(1,1,1,5,5,5-hexa­fluoro­acetyl­aceto
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✍ Preuss, Kathryn E. ;Wu, Jian ;Jennings, Michael 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 272 KB

Single-crystal X-ray study T = 100 K Mean (C±C) = 0.007 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(tetra­hydro­furan-κO)tris­(tri-tert-
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✍ Ciborska, Anna ;Chojnacki, Jaroslaw ;Wojnowski, Wieslaw 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 147 KB

In the title compound, [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ], the Cr atom has a trigonal-bipyramidal geometry, with the two tetrahydrofuran molecules in axial positions. metal-organic papers m1104 Ciborska et al. [Cr(C 12 H 27 O 4 Si) 3 (C 4 H 8 O) 2 ]