𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tetra-μ3-iodo-tetra­kis[(cyclo­hexyl­diphenyl­phosphine-κP)copper(I)]

✍ Scribed by Seddigi, Zaki S. ;Hossain, G. M. Golzar ;Banu, Afroza


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
209 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


The molecule of the title compound, [Cu~4~I~4~(C~18~H~21~P)~4~], which lies on a crystallographic twofold rotation axis, displays a cubane-like Cu~4~I~4~ core.


📜 SIMILAR VOLUMES


Tetra-μ3-iodo-tetra­kis[(tri-p-tolyl­pho
✍ Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 166 KB

The title compound [Ag 4 I 4 (C 21 H 21 P) 4 ], crystallizes on a centre of symmetry. Each Ag atom is surrounded by one phosphine ligand and three iodide anions, forming a distorted tetrahedral configuration. The Ag-P distance is 2.4666 (7) A ˚and the Ag-I distances are 2.7972 (6), 2.8322 (10) and 3

Tetra-μ3-iodo-tetra­kis­[(tri-tert-butyl
✍ Medina, Iliana ;Mague, Joel T. ;Fink, Mark J. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 162 KB

The title compound, [Cu 4 I 4 (C 12 H 27 P) 4 ], recovered from an attempt to prepare triisopropylsilylthiolato(tri-tert-butylphosphine)copper(I), is found to be tetrameric with a distorted heterocubane structure, one of the body diagonals of the cube being a crystallographic threefold rotation axis

Redetermination of bis­(acetonitrile-κN)
✍ Orto, Peter J. ;Nichol, Gary S. ;Zheng, Zhiping 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 146 KB

The crystal structure of the cluster compound, __trans__-[Re~6~Se~8~(MeCN)~2~(Et~3~P)~4~](SbF~6~)~2~, originally determined at room temperature [Zheng, Gray & Holm (1999). __Inorg. Chem.__ 38, 4888–4895], has been redetermined at 150 K. The cation lies on a crystallographic inversion center, and the

A second polymorph of cyclo-tetra­kis­{μ
✍ Tooke, Duncan M. ;Lutz, Martin ;Spek, Anthony L. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 286 KB

The structure of the title compound, [Cu 4 (C 9 H 12 N) 4 ]ÁC 4 H 8 O, has previously been reported in the monoclinic space group C2/c. We report here the structure of a second polymorph which crystallizes in the orthorhombic space group P2 1 2 1 2 1 . The copper complex is located at a general posi

The 3,4-connected layered hybrid oxide p
✍ Ochalek, Catherine E. ;LaDuca, Robert L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 533 KB

The 3,4-connected layered hybrid oxide poly[tetrakis(l-2,4 0 0 0 -bipyridine-j 2 N:N 0 0 0 )-(l 4 -b-octamolybdato-j 4 O:O 0 0 0 :O 0 0 00 0 0 :O 0 0 00 0 00 0 0 )tetracopper(I)]