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Tetra-μ3-iodo-tetra­kis[(tri-p-tolyl­phosphine-κP)silver(I)]

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
166 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound [Ag 4 I 4 (C 21 H 21 P) 4 ], crystallizes on a centre of symmetry. Each Ag atom is surrounded by one phosphine ligand and three iodide anions, forming a distorted tetrahedral configuration. The Ag-P distance is 2.4666 (7) A ˚and the Ag-I distances are 2.7972 (6), 2.8322 (10) and 3.1956 (6) A ˚.

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In the title compound, [Cu 2 I 2 (C 21 H 21 P) 3 ], one Cu I atom is coordinated by one tri-p-tolylphosphine and two iodide ligands in a distorted trigonal-planar geometry, whereas the other Cu I atom is coordinated by two phosphine and two iodide ligands in a distorted tetrahedral geometry.