✦ LIBER ✦

Tetra-μ3-iodo-tetrakis[(tri-tert-butylphosphine)copper(I)]

✍ Scribed by Medina, Iliana ;Mague, Joel T. ;Fink, Mark J.

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 162 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805021744

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Cu 4 I 4 (C 12 H 27 P) 4 ], recovered from an attempt to prepare triisopropylsilylthiolato(tri-tert-butylphosphine)copper(I), is found to be tetrameric with a distorted heterocubane structure, one of the body diagonals of the cube being a crystallographic threefold rotation axis.

📜 SIMILAR VOLUMES

Tetra-μ3-iodo-tetrakis[(tri-p-tolylpho

Tetra-μ3-iodo-tetrakis[(tri-p-tolylphosphine-κP)silver(I)]

✍ Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 166 KB

The title compound [Ag 4 I 4 (C 21 H 21 P) 4 ], crystallizes on a centre of symmetry. Each Ag atom is surrounded by one phosphine ligand and three iodide anions, forming a distorted tetrahedral configuration. The Ag-P distance is 2.4666 (7) A ˚and the Ag-I distances are 2.7972 (6), 2.8322 (10) and 3

Tetra-μ3-iodo-tetrakis[(cyclohexyldip

Tetra-μ3-iodo-tetrakis[(cyclohexyldiphenylphosphine-κP)copper(I)]

✍ Seddigi, Zaki S. ;Hossain, G. M. Golzar ;Banu, Afroza 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 209 KB

The molecule of the title compound, [Cu~4~I~4~(C~18~H~21~P)~4~], which lies on a crystallographic twofold rotation axis, displays a cubane-like Cu~4~I~4~ core.

Tetrakis(tert-butyl isocyanide)copper(I

Tetrakis(tert-butyl isocyanide)copper(I) chloride monohydrate

✍ Imhof, Wolfgang ;Halbauer, Kathi ;Görls, Helmar 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 282 KB

The title compound, [Cu(C 5 H 9 N) 4 ]ClÁH 2 O, was obtained from the reaction of copper(II) chloride hydrate with KCN in the presence of two equivalents of tert-butylisocyanide. The reaction proceeds via the reduction of copper and the formation of (CN) 2 . The compound shows a tetrahedrally surrou

Tetrakis(tetrahydrofuran)lithium(I) μ

Tetrakis(tetrahydrofuran)lithium(I) μ3-iodo-tri-μ2-iodo-bis(triphenylphosphane)tricuprate(I)(2 Cu—Cu) tetrahydrofuran solvate

✍ Morawitz, Thorsten ;Lerner, Hans-Wolfram ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 258 KB

Tetrakis(tetrahydrofuran)lithium(I) l 3 -iodotri-l 2 -iodo-bis(triphenylphosphane)tricuprate(I)-(2 Cu-Cu) tetrahydrofuran solvate

Tetrakis(μ2-methanol)bis(methanol-κO)(

Tetrakis(μ2-methanol)bis(methanol-κO)(μ2-tri-tert-butoxysilanethiolato-κ3S:S,O)bis(tri-tert-butoxysilanethiolato-κ2S,O)tetrasodium(I)

✍ Kloskowska, Magdalena ;Chojnacki, Jarosław ;Wojnowski, Wiesław ;Becker, Barbara 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 573 KB

Bis(tetra-n-butylammonium) tetrakis[c

Bis(tetra-n-butylammonium) tetrakis[chloro(μ3-sulfido)copper(I)]tungstate(VI): a second polymorph

✍ Hossaini Sadr, Moayad ;Seyed Ahmadian, Seyed Masoud ;Brooks, Neil R. ;Clegg, Wil 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 309 KB

Tetra-μ3-iodo-tetra­kis­[(tri-tert-butyl­phosphine)copper(I)]

✦ Synopsis

Tetra-μ3-iodo-tetrakis[(tri-tert-butylphosphine)copper(I)]