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Iodo­tris(tri-p-tolyl­phosphine)silver(I)

✍ Scribed by Meijboom, Reinout


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
160 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [AgI(C 21 H 21 P) 3 ], important bond distances are: Ag-P = 2.5346 (9), 2.5562 (9) and 2.5617 (9) A ˚, and Ag-I = 2.8683 (5) A ˚. The Ag I atom is in a distorted tetrahedral environment and all bond angles are close to the ideal values.


📜 SIMILAR VOLUMES


Di-μ-iodo-bis­[pyridine­(tri-p-tolyl­pho
✍ Meijboom, Reinout ;Muller, Alfred 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 157 KB

The title compound, [Ag 2 I 2 (C 5 H 5 N) 2 (C 21 H 21 P) 2 ], has C i molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The AgÁ Á ÁAg separation in the binuclear species is 3.1130 (18) A ˚. The Ag-P

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The title compound [Ag 4 I 4 (C 21 H 21 P) 4 ], crystallizes on a centre of symmetry. Each Ag atom is surrounded by one phosphine ligand and three iodide anions, forming a distorted tetrahedral configuration. The Ag-P distance is 2.4666 (7) A ˚and the Ag-I distances are 2.7972 (6), 2.8322 (10) and 3

Di-μ-iodo-tris­(tri-p-tolyl­phosphine)-1
✍ Meijboom, Reinout 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 147 KB

In the title compound, [Cu 2 I 2 (C 21 H 21 P) 3 ], one Cu I atom is coordinated by one tri-p-tolylphosphine and two iodide ligands in a distorted trigonal-planar geometry, whereas the other Cu I atom is coordinated by two phosphine and two iodide ligands in a distorted tetrahedral geometry.

Tetra­kis(tri-p-tolyl­phosphine-κP)silve
✍ Venter, Gertruida J. S. ;Meijboom, Reinout ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.007 A R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.