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Redetermination of bis­(acetonitrile-κN)octa-μ3-selenido-tetra­kis(triethyl­phosphine-κP)­hexa­rhenium(III) at 150 K

✍ Scribed by Orto, Peter J. ;Nichol, Gary S. ;Zheng, Zhiping


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
146 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The crystal structure of the cluster compound, trans-Re~6~Se~8~(MeCN)~2~(Et~3~P)~4~~2~, originally determined at room temperature [Zheng, Gray & Holm (1999). Inorg. Chem.
38, 4888–4895], has been redetermined at 150 K. The cation lies on a crystallographic inversion center, and the SbF~6~
^−^ counter-ions are fully ordered.