The 3,4-connected layered hybrid oxide poly[tetrakis(μ-2,4′-bipyridine-κ2N:N′)(μ4-β-octamolybdato-κ4O:O′:O′′:O′′′)tetracopper(I)]
✍ Scribed by Ochalek, Catherine E. ;LaDuca, Robert L.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 533 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The 3,4-connected layered hybrid oxide poly[tetrakis(l-2,4 0 0 0 -bipyridine-j 2 N:N 0 0 0 )-(l 4 -b-octamolybdato-j 4 O:O 0 0 0 :O 0 0 00 0 0 :O 0 0 00 0 00 0 0 )tetracopper(I)]
📜 SIMILAR VOLUMES
Poly[[diaquatris(l 2 -4,4 0 0 0 -bipyridine-j 2 N,N 0 0 0 )tetrakis-(phenylacetato-jO)dinickel(II)] dihydrate]
Single-crystal X-ray study T = 296 K Mean (C-C) = 0.004 A R factor = 0.030 wR factor = 0.085 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The bis(4-ethylpyridine) adduct of dicopper(II) tetrabenzoate, [ Cu 2 (C 7 H 5 O 2 ) 4 (C 7 H 9 N) 2 ], has centrosymmetrically related square-pyramidal Cu atoms bridged by four benzoate ions; the heterocyclic ligands that occupy the apical sites are disordered.
In the crystal structure of the polymeric title compound, [Mn(C~10~H~8~N~2~)(C~10~H~8~O~5~)(H~2~O)]~__n__~, the Mn^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion and is covalently bonded (through one O atom) by the aliphatic carbox