The title complex, (C 6 H 18 N 2 )[V 2 Cl 5 (C 6 H 16 N 2 ) 2 ](C 24 H 20 B).-C 4 H 8 O, was prepared by the reaction of [V 2 Cl 3 (THF) 6 ](BPh 4 ) with [FeCl 2 (tmeda) 2 ] in the presence of one equivalent of tmeda (tmeda = N,N,N H ,N H -tetramethylethylenediamine) in methanol. The crystal structu
Tetra-μ-chloro-chloro(N,N,N′,N′-tetramethylethane-1,2-diamine)(1,1,3-trimethyl-2-imidazolium)dicopper(I)copper(II)
✍ Scribed by Butcher, Ray J. ;George, C. ;Purdy, Andrew P.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 211 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.007 A Ê R factor = 0.026 wR factor = 0.061 Data-to-parameter ratio = 21.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 300 K Mean '(C±C) = 0.012 A Ê R factor = 0.039 wR factor = 0.151 Data-to-parameter ratio = 18.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.009 A Ê R factor = 0.057 wR factor = 0.136 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title vanadium complex, [VClO(C 16 H 22 N 4 )]ClO 4 , of the tetradentate ligand N,N H -dimethyl-N,N H -bis(2-pyridylmethyl)ethane-1,2-diamine was obtained from air oxidation of a mixture of the ligand and VCl 3 in wet methanol.