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Tetra-μ-acetamidato-κ4N:O;κ4O:N-bis­[aqua­ruthenium(II,III)](Ru—Ru) nitrate

✍ Scribed by Fuma, Yasuhiro ;Ebihara, Masahiro

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
302 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title mixed-valence complex, [Ru 2 (C 2 H 4 NO) 4 (H 2 O) 2 ]NO 3 , comprises two half-cations, with Ru-Ru bond distances of 2.2829 (5) and 2.2797 (5) A ˚, and a nitrate anion. Each cation is centrosymmetric. The diruthenium cations form a two-dimensional hydrogen-bonding network via N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds. metal-organic papers Acta Cryst. (2006). E62, m2805-m2807 Fuma and Ebihara [Ru 2 (C 2 H 4 NO) 4 (H 2 O) 2 ]NO 3 m2807

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