Tetra-μ-acetamidato-κ4N:O;κ4O:N-diaquadirhodium(II,III) perrhenate
✍ Scribed by Fuma, Yasuhiro ;Ebihara, Masahiro
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 393 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Rh 2 (C 2 H 4 NO) 4 (H 2 O) 2 ][ReO 4 ], the cation lies on an inversion center and the anion on a twofold axis. The cations are connected two-dimensionally by O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen bonding. Hydrogen bonds to perrhenate ions connect the two-dimensional sheets.
📜 SIMILAR VOLUMES
The asymmetric unit of the title mixed-valence complex, [Ru 2 (C 2 H 4 NO) 4 (H 2 O) 2 ]NO 3 , comprises two half-cations, with Ru-Ru bond distances of 2.2829 (5) and 2.2797 (5) A ˚, and a nitrate anion. Each cation is centrosymmetric. The diruthenium cations form a two-dimensional hydrogen-bonding
Poly[[diaquatris(l 2 -4,4 0 0 0 -bipyridine-j 2 N,N 0 0 0 )tetrakis-(phenylacetato-jO)dinickel(II)] dihydrate]