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Tetra-μ-acetamidato-κ4N:O;κ4O:N-diaqua­dirhodium(II,III) perrhenate

✍ Scribed by Fuma, Yasuhiro ;Ebihara, Masahiro


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
393 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Rh 2 (C 2 H 4 NO) 4 (H 2 O) 2 ][ReO 4 ], the cation lies on an inversion center and the anion on a twofold axis. The cations are connected two-dimensionally by O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen bonding. Hydrogen bonds to perrhenate ions connect the two-dimensional sheets.


📜 SIMILAR VOLUMES


Tetra-μ-acetamidato-κ4N:O;κ4O:N-bis­[aqu
✍ Fuma, Yasuhiro ;Ebihara, Masahiro 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 302 KB

The asymmetric unit of the title mixed-valence complex, [Ru 2 (C 2 H 4 NO) 4 (H 2 O) 2 ]NO 3 , comprises two half-cations, with Ru-Ru bond distances of 2.2829 (5) and 2.2797 (5) A ˚, and a nitrate anion. Each cation is centrosymmetric. The diruthenium cations form a two-dimensional hydrogen-bonding