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Synthetic studies on ophiobolins

✍ Scribed by Michael Rowley; Yoshito Kishi

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 220 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80638-3

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✦ Synopsis

The tricyclic ketone 14, an ophiobolin analogue lacking only the C-ring side chain, was synthesized in optically active form; the key step was the intramolecular NiCl2/CrC12 mediated coupling of 10 to yield 11.

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