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The biosynthesis-of ophiobolins

✍ Scribed by L. Canonica; A. Fiecchi; M.Galli Kienle; B.M. Ranzi; A. Scala; T. Salvatori; E. Pella

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 314 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89847-6

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✦ Synopsis

Ophiobolins A and B (1) are substances constructed from five isoprene units linearly linked head to tail (2). In their biogenetic hypothesis Nozoe et al.

proposed that the introduction of a 3-hydroxyl substituent is accounted for by attack at 3-C by an agent which transfers OH+ (3).

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