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Biogenesis of ophiobolins. The origin of the oxygen atoms in the ophiobolins

✍ Scribed by Shigeo Nozoe; Masuo Morisaki; Kyosuke Tsuda; Shigenobu Okuda

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
202 KB
Volume
8
Category
Article
ISSN
0040-4039

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Ophiobolins A and B (1) are substances constructed from five isoprene units linearly linked head to tail (2). In their biogenetic hypothesis Nozoe et al. proposed that the introduction of a 3-hydroxyl substituent is accounted for by attack at 3-C by an agent which transfers OH+ (3).