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Synthesis of t-butyl and methyl peroxynitrate

✍ Scribed by E.F.J. Duynstee; J.G.H.M. Housmans; J. Vleugels; W. Voskuil

Book ID: 104238942
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 121 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87614-0

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✦ Synopsis

Acylperoxynitrates (R-C-OONO2) are known constituents of photochemical smog'). These compounds are supposed to be formed from acylperoxy radicals and NO2. Although alkylperoxy radicals undoubtedly play an important role in photochemical smog formation 2) and gasphase reaction of these radicals with NO2 seems likely 3) , alkyl peroxynitrates (I) have thus far not been detected in photochemical smog. From the investigations of Lachowicz 4) and ourselves') we learned that fl-nitroalkyl peroxynitrates are relatively stable compounds,Considering this it seemed worthwhile to try to synthesize some simple alkyl peroxynitrates by reaction of the alkylhydroperoxides with N205: ROOH + N205 -R-O-O-NO2

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