Expedient Synthesis of t-Butyl Azide. -A simple and economical mole-scale synthesis of t-butyl azide (II) is described, utilizing only t-butyl alcohol, aqueous sulfuric acid and sodium azide. -(BOTTARO, J. C.;
โฆ LIBER โฆ
Expedient Synthesis of t -Butyl Azide
โ Scribed by Bottaro, Jeffrey C.; Penwell, Paul E.; Schmitt, Robert J.
- Book ID
- 118248617
- Publisher
- Taylor and Francis Group
- Year
- 1997
- Tongue
- English
- Weight
- 125 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0039-7911
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Azides were converted to the corresponding carbamates using a system of 20 mol% of decaborane (B 10 H 14 ) and 20 weight% of 10% Pd/C in methanol in the presence of di-tert-butyl dicarbonate at rt in high yields and to the corresponding amines using a system of 10 mol% of decaborane and 20 weight% o
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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