The pyrolyses of cyanomethyl t-butyl sulfide and its oxygen homologue have been studied in a stirred-flow system over the temperature range 490440ยฐC and pressures between 5 and 14 Tom. In both cases, isobutene is formed as product in over 97% yield. Hydrogen sulfide is obtained in about half the amo
Gas-phase structures of di-t-butyl ether and t-butyl methyl ether
โ Scribed by Siegfried Liedle; Hans-Georg Mack; Heinz Oberhammer; Mita R. Imam; Norman L. Allinger
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 917 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0022-2860
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๐ SIMILAR VOLUMES
The pyrolysis kinetics of the title compounds has been studied in a stirred-flow reactor over the temperature range 440-530ยฐC and pressures between 5 and 14 torr. Benzyl t-butyl sulfide and phenyl t-butyl ether formed isobutene as product in over 98% yield, together with the corresponding benzyl thi
The mechanisms for the C1-initiated and OH-initiated atmospheric oxidation of t-butyl alcohol (TBA), methyl t-butyl ether (MTBE), and dimethyl ether (DME) have been determined. For TBA the only products observed are equimolar amounts of HzCO and acetone, and its atmospheric oxidation can be represen
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