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Synthesis of β=iodo-t-butyl and methyl ethers from the reaction of alkenes with t-butyl and methyl hypoiodites

✍ Scribed by Stephen A. Glover; André Goosen


Book ID
108382257
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
171 KB
Volume
21
Category
Article
ISSN
0040-4039

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The reaction of t-butyl p-tolylsulfinylacetate with glyoxyltc acid yielded maleate monoester 1, whose methylat!on afforded asymmetrlc dlester 2. Conditions in which 1 and 2 react with cyclopentadiene exhibiting htgh faoal and endo selectlvities are reported. 3.-See for example. a) P.