✦ LIBER ✦

Synthesis of phenyl [1-14C]acetylene and 1,4–diphenyl[1,4-14C2] butadiyne

✍ Scribed by Som N. Dhawan; Jacques Kagan

Publisher: John Wiley and Sons
Year: 1982
Tongue: French
Weight: 218 KB
Volume: 19
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580190304

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✦ Synopsis

Abstract

Phenyl [1‐^14^C] acetylene (0.012mCi/mmole) was synthesized in 12.5% yield from [1‐^14^C] acetic acid through [1‐^14^C] acetophenone, its semicarbazone, and 4‐phenyl‐[4‐^14^C] 1,2,3‐selenadiazole obtained by selenium dioxide oxidation. Oxidative coupling gave 1,4‐diphenyl [1,4‐^14^C~2~] butadiyne in 80% yield.

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