✦ LIBER ✦

Synthesis of cyclopentadienyl-X-13C thallium

✍ Scribed by Samuel D. Larsen; Phillip J. Vergumini; Thomas W. Whaley

Publisher: John Wiley and Sons
Year: 1975
Tongue: French
Weight: 273 KB
Volume: 11
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2590110304

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Cyaclopentadienyl thallium has been prepared with one carbon position labeled at a concentration greater than 90 atom % carbon‐13. A new method for incorporating a carbon‐13 label into cyclopentadiene is reported which relies on the reaction of the di‐Grignard reagent of 1,4‐dibromobutane with isopropyl formate^13^C. The product of this reaction, cyclopentanol‐1‐^13^C, is converted to cyclopentadienyl‐X‐^13^C thallium.

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