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Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

✍ Scribed by Robert A. Gossage; Elena Muñoz-Martínez; Gerard van Koten

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
300 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readily functionalisable dendrimer core unit. An improved synthesis of chlorotriallylsilane is also presented.

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