Synthesis of 3-nitrobenzo[a]pyrene bay-region trans-7,8-diol anti-9,10-epoxide and the corresponding N2-deoxyguanosine adduct
β Scribed by Fu, Peter P.; Wu, Yu Sun; Von Tungeln, Linda S.; Lai, Jeng Shiow; Chiarelli, Paul M.; Evans, Frederick E.
- Book ID
- 126120726
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 632 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0893-228X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The exocyclic amino groups of deoxyadenosine and deoxyguanosine readily add to C-10 of the benzo[a]pyrene 7,8-diol 9,10-epoxides at room temperature overnight in trifluoroethanol. Whereas the dG adducts are obtained as a mixture of cis-and trans-opened diastereomers, the dA adducts arise exclusively