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Synthesis of (1.fwdarw.6)-2,5-Anhydro-3,4-di-O-methyl-D-glucitol via Highly Regio- and Stereospecific Cyclopolymerization of 1,2:5,6-Dianhydro-3,4-di-O-methyl-D-mannitol with Potassium tert-Butoxide

โœ Scribed by Satoh, Toshifumi; Yokota, Kazuaki; Kakuchi, Toyoji


Book ID
126776706
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
292 KB
Volume
28
Category
Article
ISSN
0024-9297

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Synthesis of end-functionalized (1 โ†’ 6)-
โœ Toshifumi Satoh; Takahiro Miura; Takeshi Hatakeyama; Kazuaki Yokota; Toyoji Kaku ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 372 KB

## Abstract Endโ€functionalized (1โ†’6)โ€2,5โ€anhydroโ€3,4โ€diโ€__O__โ€methylโ€Dโ€glucitols (3aโ€“c) were synthesized by the anionic cyclopolymerization of 1,2:5,6โ€dianhydroโ€3,4โ€diโ€__O__โ€methylโ€Dโ€mannitol (1), followed by treatment with a terminating agent such as 4โ€vinylbenzyl (2a), oxetanyl (2b), and methacry