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Synthesis and Cation-Binding Properties of (1→6)-2,5-Anhydro-D-glucitol with 3,4-Di- O -Pentyl and Decyl Groups by Cyclopolymerization of 1,2:5,6-Dianhydro-D-mannitols

✍ Scribed by Kakuchi, Toyoji; Satoh, Toshifumi; Mata, Junji; Umeda, Satoshi; Hashimoto, Hisaho; Yokota, Kazuaki


Book ID
120594781
Publisher
Taylor and Francis Group
Year
1996
Tongue
English
Weight
604 KB
Volume
33
Category
Article
ISSN
1060-1325

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## Abstract End‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐__O__‐methyl‐D‐glucitols (3a–c) were synthesized by the anionic cyclopolymerization of 1,2:5,6‐dianhydro‐3,4‐di‐__O__‐methyl‐D‐mannitol (1), followed by treatment with a terminating agent such as 4‐vinylbenzyl (2a), oxetanyl (2b), and methacry

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The cyclopolymerization of 3,4-di-O-allyl-1,2 : 5,6-dianhydro-D-mannitol ( 1) was carried out using BF 3 rOEt 2 and t-BuOK. The polymer obtained by the polymerization with BF 3 rOEt 2 mainly consisted of (1r6)-bonded 3,4-di-O-allyl-2,5-anhydro-Dglucitol as the five-membered constitutional repeating