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Regio- and Stereospecificity in Cationic Cyclopolymerization of 1,2:5,6-Dianhydro-D-mannitols and Synthesis of Poly[(1.fwdarw.6)-2,5-anhydro-3,4-di-O-ethyl-D-glucitol]

✍ Scribed by Kakuchi, Toyoji; Satoh, Toshifumi; Umeda, Satoshi; Hashimoto, Hisaho; Yokota, Kazuaki

Book ID: 127176672
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 540 KB
Volume: 28
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00116a003

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## Abstract End‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐__O__‐methyl‐D‐glucitols (3a–c) were synthesized by the anionic cyclopolymerization of 1,2:5,6‐dianhydro‐3,4‐di‐__O__‐methyl‐D‐mannitol (1), followed by treatment with a terminating agent such as 4‐vinylbenzyl (2a), oxetanyl (2b), and methacry