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“Living” Nature in Anionic Cyclopolymerization of 1,2:5,6-Dianhydro-3,4-di- O -methyl- d -mannitol Using the Potassium tert -Butoxide/18-Crown-6 Initiating System

✍ Scribed by Hatakeyama, Takeshi; Kamada, Masatoshi; Satoh, Toshifumi; Yokota, Kazuaki; Kakuchi, Toyoji


Book ID
126135627
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
104 KB
Volume
31
Category
Article
ISSN
0024-9297

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Synthesis of end-functionalized (1 → 6)-
✍ Toshifumi Satoh; Takahiro Miura; Takeshi Hatakeyama; Kazuaki Yokota; Toyoji Kaku 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 372 KB

## Abstract End‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐__O__‐methyl‐D‐glucitols (3a–c) were synthesized by the anionic cyclopolymerization of 1,2:5,6‐dianhydro‐3,4‐di‐__O__‐methyl‐D‐mannitol (1), followed by treatment with a terminating agent such as 4‐vinylbenzyl (2a), oxetanyl (2b), and methacry