Anionic Cyclopolymerization of 1,2:5,6-Dianhydro-3,4-di- O -methyl- l -iditol Leading to (6→1)-2,5-Anhydro-3,4-di- O -methyl- d -glucitol
✍ Scribed by Satoh, Toshifumi; Hatakeyama, Takeshi; Umeda, Satoshi; Kamada, Masatoshi; Yokota, Kazuaki; Kakuchi, Toyoji
- Book ID
- 126811888
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 212 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
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## Abstract End‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐__O__‐methyl‐D‐glucitols (3a–c) were synthesized by the anionic cyclopolymerization of 1,2:5,6‐dianhydro‐3,4‐di‐__O__‐methyl‐D‐mannitol (1), followed by treatment with a terminating agent such as 4‐vinylbenzyl (2a), oxetanyl (2b), and methacry
Reductive cleavage of fully methylated, partially O-carboxymethylated cellulose had previously been shown to produce 4-O-acetyl-1,5-anhydro-2,3,6-tri-O-methyl-, -2-O-(methoxycarbonylmethyl)-3,6-di-O-methyl-, -3-O-(methoxycarbonylmethyl)-2,6-di-O-methyl-, -6-O-(methoxycarbonylmethyl)-2,3-di-O-methyl-