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Synthesis of 1-chlorophosphirenes in the coordination sphere of tungsten

✍ Scribed by Bernard Deschamps; François Mathey


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
209 KB
Volume
26
Category
Article
ISSN
0040-4039

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Oxidative fluorination of P-H bonds in t
✍ Frank Bienewald; Ngoc Hoa Tran Huy; François Mathey 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 387 KB

The reaction of triphenylcarbenium tetrafluoroborate with primary or secondary phosphine pentacarbonyltungsten complexes gives the corresponding mono or diflurorophosphine complexes. The mechanism probably involves transient phosphenium complexes. The reaction is compatible with P-O but not with P-N