Generation and Stabilization of Phosphanyl- and Arsanylketenes within the Coordination Sphere of Tungsten
β Scribed by Priv.-Doz. Dr. Fritz Roland Kreissl; Mathias Wolfgruber; Werner Sieber; Priv.-Doz. Dr. Helmut Guido Alt
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 179 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Bis(diisopropylamino)(trimethylstannyl)phosphane (2) reacts the enamine 8 (92 % yield), while addition of sodium methoxide followed by thermolysis of the resulting with the (chloromethylene)diisopropylammonium salt 1 affording the C-phosphanyl-substituted iminium salt 3 (67 % hemiaminal 9 (90 % yiel
The analysis of thermal stability ofhollou spheres with internal heat generation is rendered mathematically~feasihle by ullowiny the thermal conductivity of the sphere material to uary incersely as the,fourth power q/the radius. Subjected to.fioe combinations of houndarl conditions, a hollow sphere