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Reactions of (phosphine)pentacarbonyltungsten. Synthesis of primary and secondary phosphines in the coordination sphere of tungsten

✍ Scribed by Françoi Nief; François Mercier; François Mathey

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
572 KB
Volume
328
Category
Article
ISSN
0022-328X

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The nature of the products from the reaction of TrtPH 2 (1) with an equimolar amount of phosgene strongly depends on the solvent. The initial intermediate 2 was isolated from toluene, but lost CO in dichloromethane, and HCl in diethyl ether, yielding TrtP(H)Cl (3), and (TrtPCO) 2 (4 b), respectively