Reactions of primary and secondary phosphines with aldehydes and ketones
β Scribed by M. Epstein; S.A. Buckler
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- French
- Weight
- 843 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
The nature of the products from the reaction of TrtPH 2 (1) with an equimolar amount of phosgene strongly depends on the solvent. The initial intermediate 2 was isolated from toluene, but lost CO in dichloromethane, and HCl in diethyl ether, yielding TrtP(H)Cl (3), and (TrtPCO) 2 (4 b), respectively
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