Oxidative fluorination of P-H bonds in the coordination sphere of tungsten
✍ Scribed by Frank Bienewald; Ngoc Hoa Tran Huy; François Mathey
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 387 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1387-1609
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✦ Synopsis
The reaction of triphenylcarbenium tetrafluoroborate with primary or secondary phosphine pentacarbonyltungsten complexes gives the corresponding mono or diflurorophosphine complexes. The mechanism probably involves transient phosphenium complexes. The reaction is compatible with P-O but not with P-N bonds. 0 1999 Academic des sciences / Editions scientifiques et medicales Elsevier SAS * Correspondence and reprints. 1387-1609/99/000207010 1999 Acad&nie des sciences I l?ditions scientifiques et mbdicaks Else&x SAS. Tow droits rbern?s
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