The reaction of triphenylcarbenium tetrafluoroborate with primary or secondary phosphine pentacarbonyltungsten complexes gives the corresponding mono or diflurorophosphine complexes. The mechanism probably involves transient phosphenium complexes. The reaction is compatible with P-O but not with P-N
✦ LIBER ✦
Facile double-bond migration of allylsilanes in the coordination sphere of tungsten complexes
✍ Scribed by Bożena Adrjan; Teresa Szymańska-Buzar
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 431 KB
- Volume
- 297
- Category
- Article
- ISSN
- 1381-1169
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