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Novel Trimerization of Phosphaalkynes in the Coordination Sphere of Ruthenium Complexes

โœ Scribed by Dr. Peter B. Hitchcock; Dr. Cameron Jones; Prof. John F. Nixon


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
384 KB
Volume
33
Category
Article
ISSN
0044-8249

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Novel Reactions of Phosphaalkynes in the
โœ Frank Tabellion; Anja Nachbauer; Stefan Leininger; Christoph Peters; Fritz Preus ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 107 KB ๐Ÿ‘ 2 views

A small variation in the vanadium reagent leads to a completely different product: The cyclooligomerization of phosphaalkynes 2 with tBuN=VCl โ‹…DME (DME=1,2-dimethoxyethane) proceeds with incorporation of the imido fragment to give the azatetraphosphaquadricyclanes 1. In contrast, with the correspond