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Synthesis and spectroscopic characterisation of 13C-labelled ubiquinone-0 and ubiquinone-10

✍ Scribed by W.B.S. van Liemt; W.F. Steggerda; R. Esmeijer; J. Lugtenburg

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 940 KB
Volume: 113
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19941130305

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✦ Synopsis

Abstract

(1‐^13^C)‐, (2‐^13^C)‐, (3‐^13^C)‐, (3‐^13^CH~3~)‐, (4‐^13^C), and (^13^CH~3~O)~2~‐ ubiquinone‐10 and the corresponding (1‐^13^C)‐, (6‐^13^C)‐, (5‐^13^C)‐, (5‐^13^CH~3~)‐, (4‐^13^C)‐, and (^13^CH~3~O)~2~‐ubiquinone‐0 have been synthesised from simple labelled starting materials via a single reaction scheme. The ubiquinones have been characterised using mass spectrometry, ^1^H NMR and ^13^C NMR. The spectroscopic results indicate that, within experimental error, the syntheses have been accomplished without scrambling or dilution of label. All labelled ubiquinones have been synthesised on a decigram scale.

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