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Synthesis and Spectroscopic Characterization of [5-13C]- and [6-13C]Ubiquinone-10 for Studies of Bacterial Photosynthetic Reaction Centers

✍ Scribed by Rutger B. Boers; Peter Gast; Arnold J. Hoff; Huub J. M. de Groot; Johan Lugtenburg

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
444 KB
Volume
2002
Category
Article
ISSN
1434-193X

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✦ Synopsis

This paper presents the synthesis and characterization by mass spectrometry and NMR spectroscopy of [2-13 C]-and [3-13 C]ubiquinone-0 and of [5-13 C]-and [6-13 C]ubiquinone-10. A scheme based on the synthetic approach to [5-13 C]ubiquinone-10 has been worked out for the synthesis of ubiquinones 13 C-labeled at any individual position and at every combination of positions in the quinone ring. The [5-13 C]and [6-13 C]ubiquinone-10 isotopomers were incorporated

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