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Synthesis and 1H and 13C NMR study of the stereochemistry of (E )-2-acetyl-3-aryl-7-arylidene-3,3a,4,5,6,7-hexahydroindazoles

✍ Scribed by V. Vijayabaskar; S. Perumal; S. Selvaraj; M. J. E. Hewlins

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 113 KB
Volume: 37
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199901)37:1<65::aid-mrc390>3.0.co;2-h

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✦ Synopsis

The reaction of 2,6-diarylidenecyclohexanones with hydrazine hydrate in glacial acetic acid resulted in the formation of diastereomers of (E)-2-acetyl-3-aryl-7-arylidene-3,3a,4,5,6,7-hexahydroindazoles. The relative conÐgurations of these diastereomers were unambiguously assigned using 1H and 13C NMR spectroscopic methods.

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