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Synthesis and Screening of New Chiral Ligands for the Copper-Catalyzed Enantioselective Allylic Substitution.

โœ Scribed by Sandrine Ongeri; Umberto Piarulli; Maryline Roux; Chiara Monti; Cesare Gennari


Publisher
John Wiley and Sons
Year
2003
Weight
162 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


๐Ÿ“œ SIMILAR VOLUMES


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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-