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ChemInform Abstract: New Chiral Phosphinooxazolidine Ligands for Palladium-Catalyzed Asymmetric Allylic Substitution.

✍ Scribed by Myung-Jong Jin; Jung-Ae Jung; Sang-Han Kim

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity.

-(JIN, MYUNG-

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