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ChemInform Abstract: New Chiral Phosphinooxathiane Ligands for Palladium-Catalyzed Asymmetric Allylic Substitution Reactions.

✍ Scribed by Hiroto Nakano; Yuko Okuyama; Hiroshi Hongo


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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ChemInform Abstract: New Chiral Phosphin
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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-