P-Chiral Monodentate Diamidophosphites — New and Efficient Ligands for Palladium-Catalyzed Asymmetric Allylic Substitution.
✍ Scribed by Vasily N. Tsarev; Sergey E. Lyubimov; Alexei A. Shiryaev; Sergey V. Zheglov; Oleg G. Bondarev; Vadim A. Davankov; Anzhelika A. Kabro; Sergey K. Moiseev; Valery N. Kalinin; Konstantin N. Gavrilov
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 168 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Novel __P__\*‐chiral __P__,__N__‐bidentate ligands were synthesized by treatment of ferrocene‐based imino alcohols with chlorophosphites derived from (__S__)‐2‐anilinomethylpyrrolidine or (__S__)‐prolinol. Metal chelate complexes with the ligands – [Rh(CO)(PN)Cl] and [Pd(PN)(allyl)]^+^X