P-Chiral Monodentate Diamidophosphites − New and Efficient Ligands for Palladium-Catalysed Asymmetric Allylic Substitution
✍ Scribed by Vasily N. Tsarev; Sergey E. Lyubimov; Alexei A. Shiryaev; Sergey V. Zheglov; Oleg G. Bondarev; Vadim A. Davankov; Anzhelika A. Kabro; Sergey K. Moiseev; Valery N. Kalinin; Konstantin N. Gavrilov
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 169 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-193X
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## Abstract Novel __P__\*‐chiral __P__,__N__‐bidentate ligands were synthesized by treatment of ferrocene‐based imino alcohols with chlorophosphites derived from (__S__)‐2‐anilinomethylpyrrolidine or (__S__)‐prolinol. Metal chelate complexes with the ligands – [Rh(CO)(PN)Cl] and [Pd(PN)(allyl)]^+^X
## Abstract A family of monodentate polystyrene‐supported phosphites, phosphoramidites and phosphanes has been prepared and evaluated as ligands in rhodium‐catalysed asymmetric hydrogenation and palladium‐catalysed asymmetric allylic alkylation. The supported ligands yielded active and enantioselec
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v